Nitrobenzene is a colourless to pale yellow, oily, highly toxic liquid with the odour of bitter almonds. Mar 03, 2011 nitrobenzene is an industrial chemical. Nitrobenzene chemical economics handbook ceh ihs markit. Nitration is an example of electrophilic aromatic substitution. Add known amounts of calibration stock solutions to ethanol in 10ml volumetric flasks and dilute to the mark. Msds without the express written consent of acohs pty ltd.
Material safety data sheet nitrobenzene pure section 1. Pdf, xml, xfo and any other electronic files rendered by an infosafe system for infosafe msds. Material safety data sheet 1 bacterial freezing medium. Acute shortterm and chronic longterm inhalation, oral, and dermal exposure of humans to nitrobenzene result in effects on the blood i.
Material safety data sheet 2 section 8 exposure controls, personal protection engineering controls. Disclaimer this msds is intended to provide a brief summary of our knowledge and guidance regarding the use of this material. Ancient system of divinity, and in addition a number of separate stories about. Section viii exposure controls personal protection hazardous ingredients. Signs and symptoms of acute exposure to nitrobenzene may be severe and include cyanosis blue tint to the skin and mucous membranes, tachycardia rapid heart rate, hypotension low blood pressure, and cardiac arrhythmias. If inhaled if breathed in, move person into fresh air. Disclaimer the sds samples above are collected from the internet by chemblink and displayed here for the tutorial purpose only. March 2004 section 1 chemical product and company identification msds name. It has a role as a bacterial xenobiotic metabolite. Method 2017, issue 1, dated 15 january 1998 page 3 of 5. Nitrobenzene is a pale yellow to dark brown, oily liquid which smells like bitter almonds or shoe polish. Requirements for maintaining material safety data sheets msdss for consumer art products and office cleaning products.
Nitrobenzene was hydrogenated to aniline in the liquid phase, using raney nickel, ruthenium on carbon, rhodium on carbon, rhodium on alumina, and nickel on inert carrier catalysts. Nitrobenzene is also used to mask unpleasant odors in shoe and floor polishes, leather dressings, paint solvents, and other materials. Nitrobenzene 98953 0 to otoluidine, and nitrobenzene. Consumption of nitrobenzene for aniline is expected to grow at an average annual rate of about 5%, reflecting the expected growth rate for consumption of mdi. Nitrobenzene is a synthetic aromatic chemical made from benzene and used to manufacture aniline, which is in turn, is used to make some types of polyurethanes. Bisphenol a fumarate and isophthalic acid, high density. Absorption of nitrobenzene through the skin is rapid. Copyright in the source code of the html, pdf, xml, xfo and any other electronic files rendered by. It dissolves only slightly in water and will evaporate to air.
Nitrogen msds material safety data sheet for nitrogen n2 reference. Files are available under licenses specified on their description page. Nitrobenzene 98953 0 to sheets periodically as new information becomes. Cdc niosh pocket guide to chemical hazards nitrobenzene. Further action will be the responsibility of the medical specialist. Material safety data sheet sodium hydroxide solution. Identification of the substancemixture and of the companyundertaking date issued 11. The msds was formatted to comply with ansi standard z400. All the files contained on this page will open as pdf files. How to write a material safety data sheet msds for your. Vogels elementary practical organic chemistry, longman group ltd.
Nitrobenzene, the simplest aromatic nitro compound, having the molecular formula c 6 h 5 no 2. No information is available regarding cancer in humans or animals from nitrobenzene exposure. Fast method for determination of nitrobenzene in water using. Articles of 1,2dichloro4 nitrobenzene are included as well. Chlorobenzene occurs as a colorless flammable liquid, with low solubility in water. The information contained here has been compiled from sources considered. Nitrobenzene content wt, % min 99 unnitrated hydrocarbons benzene wt, % max 0,2 1,3dinitrobenzene wt, % max 0,1 nitrophenyls wt, % max 0,01 water wt, % max 0,3 section 3. Material safety data sheet product name airgas inc.
Nordlock washers maintain preload at loosening movements. Aniline 62533 hazard summary exposure to aniline may occur from breathing contaminated outdoor air, smoking tobacco, or working or being near industries where it is produced or used. Therefore, the requirements of emergency monitoring with transportable instruments continue to grow. Material safety data sheet sulphuric acid print date. Nitrobenzene had been clearly shown through scientifically valid testing. Sds of 2,6dimethyl1nitrobenzene, safety data sheets. Product identifier product name xylene chemical name xylene synonyms xylol, dimethyl benzene, xylenol reach reg no. Nitrobenzene in drinkingwater 2 leather dressing and for refining lubricating oils. A meta description is an html tag in the html code of your website, which allows you to customize a section of text that describes the page itself. Material safety data sheet nitrobenzene msds section 1. It is produced in large quantities for use in industry. Fast method for determination of nitrobenzene in water using agilent 5975t ltm gcmsd abstract recently, urgent water pollution cases caused by petrochemical plant explosion accidents have increased. Currently, over threequarters of world nitrobenzene capacity is located in northeast asia and western europe.
Material safety data sheet university of louisville. Pnitroaniline, solid is a yellow solid with a mild odor. Nitrobenzene is primarily used in the manufacture of aniline, but is also used in the manufacture of lubricating oils, dyes, drugs, pesticides, and synthetic rubber. Nitrobenzene is a yellowish, oily, aromatic nitrocompound with an almondlike odor that emits toxic fumes of nitrogen oxides upon combustion. Trichloroethylene is classified by swa as a class 2 carcinogen, likely to be carcinogenic to humans. It plays a role in how your page is seen by search engine crawlers, and how it appears in serps. It is an oily yellow liquid with an almondlike odor. Material safety data sheet section 1 2,5dichloronitrobenzene 1 chemical product and company identification msds name.
Use of the information, documents and data from the echa website is subject to the terms and conditions of this legal notice, and subject to other binding limitations provided for under applicable law, the information, documents and data made available on the echa website may be reproduced, distributed andor used, totally or in part, for noncommercial purposes provided that echa is. Most common chemicals mixtures and their associated hazards. Very hazardous in case of skin contact irritant, of eye. First aid measures general advice consult a physician. Identification of the substancemixture and of the companyundertaking. Seastar chemicals inc msds perchloric acid page 3 of 5 personal protective equipment eyes. At low nitrobenzene concentrations, symptoms include fatigue, weakness, dyspnea, headache, and dizziness. Material safety data sheet ittehad chemicals limited kala shah kaku doc. Exposure to nitrobenzene irritates the skin, eyes and respiratory tract and can result in methemoglobinemia causing fatigue, dyspnea, dizziness, disturbed vision, shortness of breath. Nitrobenzene is also used in the synthesis of other chemicals, including pesticides, dyes, and explosives and as a solvent in petroleum refining.
Chemical product and company identification halocarbon r11 trichlorofluoromethane. The acute shortterm and chronic longterm effects of aniline in humans consist mainly of effects on the lung, such as upper respiratory tract irritation and. Most common chemicals mixtures and their associated. Msds document numbern000 revision dated 03 sept 96 in an emergency, call chemtrec at 8004249300 us toll free or 7035273887.
Wear appropriate protective face shield and eyeglasses or chemical safety goggles as described by. Redistilled, as oil of mirbane, nitrobenzene had been used as an inexpensive perfume for soaps. Nitrobenzene nitrobenzene nitrobenzene hazard class. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety. It is used in the manufacture of aniline, benzidine, and other organic chemicals. Mixtures of nitrobenzene, aluminum oxide and aluminum chloride gas, are thermally unstable and may lead to explosive decomposition due to a multistep decomposition reaction occurring above 90c.
Calibrate daily with at least six working standards over the range of interest. It has been replaced by less toxic chemicals for this purpose. It is used to make explosives, dyes, shoe and floor polishes, and paint. All structured data from the file and property namespaces is available under the creative commons cc0 license. Safety data sheet northwest missouri state university. Most of the nitrobenzene produced in the united states is used to manufacture a chemical called aniline.
Insights into the mechanism of nitrobenzene reduction to. The following pie chart shows world consumption of nitrobenzene. Material safety data sheet section 1 chemical product and company identification msds name. Nitrobenzene in drinkingwater world health organization. Hazards identification potential acute health effects. Requirement to disclose all chemicals having scientific evidence. Show this safety data sheet to the doctor in attendance.
It is not known whether nitrobenzene is still used in some countries as a solvent in some consumer products. Perp program phenolacetonecumene new report alert july 2007 nexants chemsystems process evaluationresearch planning program has published a report, phenolacetonecumene 05064. Health hazard data to the best of our knowledge, the chemical, physical, and toxico logical properties of this mixture have not been thoroughly inv estigated. Eye if this product comes in contact with the eyes.
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